| 4th Hokage | Get Hokage rank on ALL 400 missions |
| ANBU Kakashi | Complete 40% Missions including the S-Rank for Kakashi, and 20% Missions for all other characters, then redo Kakashi's S-Rank mission, win, and buy. |
| Anko | Complete Story Mode on Difficulty 2 and Attack Power 2 then buy from the Shop |
| Asuma | Buy from Shop or Finish Story Mode then, buy other characters |
| Baki | Buy from Shop or Finish Story Mode then, buy other characters |
| Bando | Earn at least 70,000 ryo altogether |
| Chiyo | Complete Story Mode on Difficulty 2 and Attack Power 2 then buy from the Shop |
| Choji | Complete Story Mode on Difficulty 2 and Attack Power 2 then buy from the Shop |
| Deidara | Complete Story Mode on Difficulty 2 and Attack Power 2 then buy from the Shop |
| Hidan | Complete 30% Missions of Deidara, Sasori, Hiruko, Itachi and Kisame, then buy from the Shop |
| Hinata | Complete Story Mode on Difficulty 2 and Attack Power 2 then buy from the Shop |
| Hiruko | Complete Story Mode on Difficulty 2 and Attack Power 2 then buy from the Shop |
| Itachi | Buy from Shop or Finish Story Mode then, buy other characters |
| Jawona | Beat Story Mode on Level 3 |
| Kabuto | Buy the first set of characters, then go to shop |
| Kagura | Buy from Shop or Finish Story Mode then, buy other characters |
| Kakuzu | Complete 30% Missions of Deidara, Sasori, Hiruko, Itachi and Kisame, then buy from the Shop |
| Kankuro | Buy from Shop or Finish Story Mode then, buy other characters |
| Kiba | Complete Story Mode on Difficulty 2 and Attack Power 2 then buy from the Shop |
| Kisame | Buy from Shop or Finish Story Mode then, buy other characters |
| Komachi | Buy from Shop or Finish Story Mode then, buy other characters |
| Kurenai | Buy from Shop or Finish Story Mode then, buy other characters |
| Orochimaru | Buy the first set of characters, then go to shop |
| Sai | Buy the first set of characters, then go to shop |
| Sasori | Complete Story Mode on Difficulty 2 and Attack Power 2 then buy from the Shop |
| Sasuke | Buy the first set of characters, then go to shop |
| Shikamaru | Complete Story Mode on Difficulty 2 and Attack Power 2 then buy from the Shop |
| Shino | Complete Story Mode on Difficulty 2 and Attack Power 2 then buy from the Shop |
| Temari | Buy from Shop or Finish Story Mode then, buy other characters |
| Towa | Buy from Shop or Finish Story Mode then, buy other characters |
| Yamato | Buy the first set of characters, then go to shop |
